Books etc

Stable organic radicals have drawn attention as promising building blocks for multifunctional materials. In order to realize the tailored magnets based on molecular materials, it is necessary to investigate magneto-structural correlation of open-shell molecules. In the present chapter, we describe the magnetic property of dihydroquinoline N-oxyl-based radicals and benztriazynyl-based radicals to discuss the substituent effect on molecular packing and intermolecular magnetic interaction. Relatively large magnetic interactions were observed through π-π stacking for dihydroquinoline N-oxyl-based radicals. Spin transition behavior was demonstrated in benztriazynyl-based radical.

水素結合を駆動力とした自己集積型安定有機ラジカルのデータをもとに強磁性有機固体の構築を目指した分子配列の制御法について解説した。

高分子金属錯体をスピン化学の立場から分類し、分子性化合物におけるスピン整列のメカニズムおよび分子性磁性材料の設計法を総論的に解説した。